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Observation of Charge Transfer Complex Orientational Phase Transitions by Means of Fourier Transform Infrared Spectroscopy

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Abstract:

Fourier transform infrared spectroscopy was used to monitor the ∼200 K order-disorder phase transition of anthracene-h10:tetracyanobenzene and anthracene-d10:tetracyanobenzene charge transfer complexes. It was shown that the technique is sufficiently sensitive to monitor the temperature of transition and to study the transition via the infrared active internal vibrational modes.

Keywords: Charge transfer complex; Fourier transform infrared spectroscopy; Molecular structure

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702814731833

Affiliations: 1: Division of Chemistry, National Research Council of Canada, Ottawa, Ontario, Canada K1A OR6 2: Division of Chemistry, National Research Council of Canada, Ottawa, Ontario, Canada K1A OR6; on leave of absence from the Institute for Chemical Research, Kyoto University, Uji, Kyoto-fu, 611 Japan

Publication date: January 1, 1981

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