Raman Studies of the Adduct Structure of Cl2 and Br2 with Piaselenole

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Abstract:

The affinity of 2,1,3-benzoselenadiazole, commonly called piaselenole, for chlorine and bromine molecules has been known for a long time. Raman spectroscopy provides a very interesting method for determining the molecular structure of these 1:1 adducts. The Raman spectrum shows the Cl2 and Br2 molecules in the adduct remain as a dimer molecule.

Keywords: Matrix isolation; Raman spectroscopy; Structure analysis

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702804731177

Affiliations: 1: Department of Chemistry, Kansas State University, Manhattan, Kansas 66506; present address: National Bureau of Standards, Washington, DC 2: Department of Chemistry, Kansas State University, Manhattan, Kansas 66506

Publication date: November 1, 1980

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