An X-ray Photoelectron (ESCA) and Laser Raman Spectroscopic Investigation of Aluminum Perrhenate

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Abstract:

Compound formation in supported heterogeneous catalysts is an area of significant interest. In the present study, Al(ReO4)3 was prepared and characterized by x-ray photoelectron spectroscopy and laser Raman spectroscopy. Characteristic spectra Al(ReO4)3 for are shown and compared to several rhenium reference compounds. The reduction behavior of Al(ReO4)3 is also explored; it was completely reduced to elemental rhenium in H2 at 500°C.

Keywords: Aluminum perrhenate; Laser raman spectroscopy; Rhenium; X-ray photoelectron spectroscopy

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702804731087

Affiliations: Department of Chemistry, University of Pittsburgh, Pittsburgh, Pennsylvania 15260

Publication date: November 1, 1980

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