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Interaction between CO Stretching and Overtone of CD Out-of-plane Bending Observed in the Infrared Spectra of Deuteroformyl Compounds

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Dahlqvist and Euranto reported an apparent doubling of the infrared carbonyl stretching band of a number of alkyl deuteroformate esters. By comparison with the corresponding protioformate esters and a process of elimination, they showed that the apparent CO band at higher frequencies must be the overtone of CD out-of-plane bending ("2 × CD op be") in Fermi resonance with CO stretching ("CO st").

Keywords: Carbonyl bands; Deuteroformyl compounds; Fermi resonance; Infrared spectra

Document Type: Short Communication

DOI: http://dx.doi.org/10.1366/0003702794924959

Affiliations: Medical Chemistry Group, Australian National University, Canberra, A.C.T. 2600.

Publication date: November 1, 1979

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