Spectroscopy of Transient Species and Molecular Ions in Matrices

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Matrix-isolation spectroscopy is particularly useful for the study of transient species and molecular ions. New methods for producing and trapping reactive molecules for spectroscopic characterization are described. Matrix investigations of charge-transfer anionic species, free radicals, positive ions, and van der Waals molecules are discussed.

Keywords: Free radicals; Matrix-isolation spectroscopy; Molecular ions

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/0003702794925877

Affiliations: Chemistry Department, McCormick Road, University of Virginia, Charlottesville, Virginia 22901

Publication date: May 1, 1979

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