Raman Spectra of Possible Corrosion Products of Iron

Authors: Thibeau, Richard J.; Brown, Chris W.; Heidersbach, Robert H.

Source: Applied Spectroscopy, Volume 32, Issue 6, Pages 527-593 (November/December 1978) , pp. 532-535(4)

Publisher: Society for Applied Spectroscopy

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Abstract:

Raman spectra of FeO, Fe3O4, α-Fe2O3, α-FeOOH, and γ-FeOOH, the common products of iron oxidation, have been measured. The spectra of FeO and Fe3O4 appear to be identical. Armco iron oxidized in air at 250°C was examined by Raman spectroscopy after varying periods of exposure and the surface film was found to contain Fe3O4 and α-Fe2O3.

Keywords: Raman spectroscopy; iron oxide, corrosion

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/000370278774330739

Affiliations: Department of Chemistry, University of Rhode Island, Department of Ocean Engineering, University of Rhode Island, Kingston, Rhode Island 02881

Publication date: November 1, 1978

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