Raman Scattering from Molecular Rubidium

Authors: Baierl, P.1; Kiefer, W.2

Source: Applied Spectroscopy, Volume 32, Issue 2, Pages 145-252 (March/April 1978) , pp. 240-243(4)

Publisher: Society for Applied Spectroscopy

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Abstract:

Most of the alkali dimers have been the subject of numerous spectroscopic investigations. For the lighter homonuclear diatomic molecules Li2, Na2, and K2 spectroscopic constants have been precisely determined by laser excited photoluminescence spectroscopy. However, because of relatively small vibrational and rotational constants of the heavier species, the ground state molecular parameters and potential curves for Rb2 and Cs2 are not so easy to determine. We have started to make a Raman spectroscopic study of Rb2 in order to determine independently from excited electronic state data the vibrational energy of the X1Σg + ground state.

Keywords: Fluorescence; Light scattering; Raman spectroscopy

Document Type: Short Communication

DOI: http://dx.doi.org/10.1366/000370278774331530

Affiliations: 1: Sektion Physik der Universität München, Lehrstuhl Prof. J. Brandmüller, Schellingstr. 4, D-8000 München 40, F.R.G. 2: Sektion Physik der Universität München, Lehrstuhl Prof. J. Brandmüller, Schellingstr. 4, D-8000 München 40, F.R.G.; present address: Physikalisches Institut, Universität Bayreuth, D-8580 Bayreuth, F.R.G.

Publication date: March 1, 1978

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