Direct Recording of Intermolecular Interaction Perturbation Spectra by Fourier Transform Spectroscopy

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Abstract:

The symbiosis of the Fourier transform spectrometer with the computer permits the development of novel procedures for handling spectroscopic data. Two such procedures are here described. The first one produces directly the spectrum of the intermolecular interaction perturbation in solutions, while the second obtains the spectrum of pressure broadening coefficients of a gas sample. The interpretation of these techniques are discussed in the light of experimental results and shown to be critically dependent on a constant, well defined slit function and on nearly perfect spectral and intensity registration.

Keywords: Computer applications; Computer processing; Fourier transform spectroscopy; Infrared; Infrared, general; Instrumentation; Perturbation spectra

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/000370275774455897

Affiliations: Block Engineering, 19 Blackstone St., and Digilab, 237 Putnam Ave., Cambridge, Massachusetts 02139

Publication date: July 1, 1975

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