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Ligand-Field Transitions in Tetrahedral Tetrabromo-Iron(III) Complex Ions in Molten tetra-n-Butylphosphonium Bromide

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Abstract:

The spectrum of iron (III) chloride has been measured in molten metal chlorides and nitrate eutectics. Gruen has suggested a strong absorption band below 25,000 cm−1 in the latter. In the case of chloride eutectic a strongly absorbing shoulder has been found below 25,000 cm−1. These results appear to be inconclusive with regard to the iron-chloride configuration.

Keywords: Fused salts; Iron; Ligand-field; Spectra

Document Type: Short Communication

DOI: http://dx.doi.org/10.1366/000370274774332597

Affiliations: Department of Chemistry, Aligarh Muslim University, Aligarh, 202001 India

Publication date: May 1, 1974

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