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The Charge Transfer to Solvent (CTTS) Spectrum of Br In Molten Tetrabutylphosphonium Tetrabromometalates

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Abstract:

Recently we reported that some of the charge-transfer bands of CoBr4 = which are ordinarily obscured by the absorption of Br can be resolved in thin films of (Bu4P+)2CoBr4 =.1 Apparently the concentration of free Br is so small under these conditions that it permits the detection of CoBr4 = bands in the same region. Here we note that it is also possible to observe at least the first component of the absorption band of Br by the same technique.

Keywords: Bromide; Charge transfer to solvent spectra; Fused salts

Document Type: Short Communication

DOI: http://dx.doi.org/10.1366/000370273774333399

Affiliations: Department of Chemistry, New York University, New York, New York 10003

Publication date: September 1, 1973

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