Charge-Transfer and the Ligand-Field Transitions in Tetrahedral Tetrabromo-Cobalt (II) Complex Ion in Molten Tetra-n-Butylphosphonium Bromide

Authors: Sundheim, B.R.; Islam, N.

Source: Applied Spectroscopy, Volume 27, Issue 4, Pages 253-289 (July/August 1973) , pp. 285-286(2)

Publisher: Society for Applied Spectroscopy

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Abstract:

In connection with studies on low melting organic salts, we had occasion to examine the optical absorption spectrum of CoBr₄⁼. In addition to the usual d-d spectra, we were also able to see some of the charge-transfer bands of this ion by utilizing the properties of the fused salt solvent.

Keywords: Fused salts; Cobalt; Charge transfer; Spectra

Document Type: Short communication

DOI: http://dx.doi.org/10.1366/000370273774333506

Affiliations: 1: Department of Chemistry, New York University, New York, New York 10003

Publication date: 1973-07-01

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