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Charge-Transfer and the Ligand-Field Transitions in Tetrahedral Tetrabromo-Cobalt (II) Complex Ion in Molten Tetra-n-Butylphosphonium Bromide

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In connection with studies on low melting organic salts, we had occasion to examine the optical absorption spectrum of CoBr4 =. In addition to the usual d-d spectra, we were also able to see some of the charge-transfer bands of this ion by utilizing the properties of the fused salt solvent.

Keywords: Charge transfer; Cobalt; Fused salts; Spectra

Document Type: Short Communication

DOI: http://dx.doi.org/10.1366/000370273774333506

Affiliations: Department of Chemistry, New York University, New York, New York 10003

Publication date: July 1, 1973

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