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Analytical Curves in Atomic Fluorescence Spectrometry

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Abstract:

The shapes of theoretical growth curves in atomic fluorescence spectrometry are calculated for several possible atomizer cell geometries, for several geometries of illumination measurement, for both line and continuum sources of excitation, and for several a parameter values. Factors relating the shapes of theoretical growth curves to experimental growth curves (analytical curves) are also discussed. Theoretical atomic fluorescence growth curves for hypothetical atoms having a parameters of 5, 2, 1, 0.4, and 0.1; for three different limiting cases characterizing the geometry of illumination measurement; and for both line and continuum sources are given.

Keywords: Damping constants; Flame atomic fluorescence spectroscopy; Flames; Growth curves

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/000370272774351741

Affiliations: 1: Department of Chemistry, University of Florida, Gainesville, Florida 32601; present address: UVVVR, Pristavni 24, Praha 7, Czechoslovakia 2: Department of Chemistry, University of Florida, Gainesville, Florida 32601

Publication date: September 1, 1972

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