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Computer Time Averaging of Laser Raman Spectra for Matrix-Isolated Species

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Abstract:

With the recent development of commercially available laser-Raman spectrometers, many previously impossible types of experiments are now being performed. One of these areas of research is the laser-Raman spectroscopy of matrix-isolated samples. In this application, relatively weak signals (from the dilute sample of interest) are measured with large amounts of background scatter from the matrix material. Thus, back-ground signals as large as 1 × 10−8 A must be suppressed while the peak signals of interest may be as small as ∼0.1 × 10−9 A; under these conditions the signal-to-noise ratio becomes the limiting factor in obtaining useful spectra.

Keywords: Computer time averaging, Raman spectra, Matrix isolation

Document Type: Short Communication

DOI: http://dx.doi.org/10.1366/000370272774351985

Affiliations: Chemistry Department, University of Virginia, Charlottesville, Virginia 22901

Publication date: July 1, 1972

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