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Identification of the O—O Stretching Frequency in Some Fluoroperoxides by Raman Spectroscopy

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Abstract:

The O—O stretching frequency in a series of fluoroperoxides was identified by Raman spectroscopy. This vibration is usually the most intense in the Raman spectrum and is highly polarized. The value of the peroxide stretching frequency was found to depend on the electro-negativity of attached groups.

Keywords: Molecular structure; O—O stretching vibration; Raman spectroscopy

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/000370272774352182

Affiliations: Corporate Chemical Research Laboratory, Allied Chemical Corporation, Morristown, New Jersey 07960

Publication date: May 1, 1972

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