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An Infrared and Raman Study of Benzylidenemalononitriles

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Infrared and Raman spectra have been determined and the nitrile and olefinic C=C stretching bands assigned for 35 benzylidenemalononitriles. The effect of aromatic ring substitution on the position of the nitrile stretching band is discussed. Data are presented relating the nitrile stretching frequency to Hammett substituent constants for meta- and para-substituted benzylidenemalononitriles in chloroform solutions.

Keywords: Benzylidenemalononitriles; Infrared spectra; Raman spectra

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/000370272774352344

Affiliations: Analytical Chemistry Department, Chemical Research Lab, Research Laboratories, Edgewood Arsenal, Maryland 21010

Publication date: March 1, 1972

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