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Vibrational Analyses of N-Substituted Aziridines. II. Sulfinylbis(1-Aziridine)

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Abstract:

The normal vibrations of sulfinylbis(1-aziridine) have been assigned assuming C s symmetry for the molecule. The ir absorption peaks arising from the sulfoxide group were identified from the measurement of frequency shifts produced by intermolecular association of the sulfoxide linkage with chloroform. The remainder of the spectra were assigned by comparison with the analogous carbonyl compound and with ethyleneimine. The spectra of sulfinylbis(1-aziridine) recorded at room temperature and 77°K suggest the existence of rotational isomers at room temperature.

Keywords: Aziridines; Infrared spectra; Raman spectra; Vibrational analysis

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/000370272774352623

Affiliations: 1: Department of Chemistry, Texas A&M University, College Station, Texas 77843; present address: Central Laboratory, The Dow Chemical Company, Texas Division, Freeport, Texas 77541 2: Department of Chemistry, Texas A&M University, College Station, Texas 77843

Publication date: January 1, 1972

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