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Confirmation of SF3 + Vibrational Assignments by Raman Spectroscopic Polarization Measurements in HF Solution

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Abstract:

The vibrational assignments of the trifluorosulfur(IV) cation (SF3 +), previously determined from spectra of solids, are confirmed by polarization measurements on solutions of SF3 +BF4 , SF3 +PF6 , and SF3 + AsF6 in anhydrous HF. Techniques and equipment have been developed to obtain Raman spectra of species dissolved in anhydrous hydrogen fluoride. Accurate polarization information can be obtained even though the FEP fluorocarbon plastic used as a container-and window material is optically active.

Keywords: Assignments; Hydrogen fluoride; Polarization measurements; Raman spectroscopy; Trifluorosulfur(IV) cation

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/000370272774352533

Affiliations: Department of Inorganic and Analytical Chemistry, The Hebrew University of Jerusalem, Jerusalem, Israel

Publication date: January 1, 1972

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