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A Polycrystalline Thin-Film Technique for Infrared Transmission Studies of Alkali Halogenates

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Abstract:

Polycrystalline thin films of alkali halogenates have been prepared by a solvent-evaporation technique. Refinement of the technique has enabled us to produce a uniform thin film free of the Christiansen effect. The film thicknesses have been measured by x-ray fluorescence to be from 0.4 to 1.0 μ, with an estimated error of less than 2%. The technique is based on the deposition of a thin film on a high-density polyethylene substrate making it possible to study quantitatively the external vibrational modes and those internal modes of potassium and sodium halogenates which have a resonant frequency of less than 600 cm−1

Keywords: Infrared; Thin films; Transmission

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/000370271779951020

Affiliations: Department of Chemistry and Hawaii Institute of Geophysics, University of Hawaii, Honolulu, Hawaii 96822

Publication date: November 1, 1971

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