Observation of Hot Bands in the Raman Spectra of Cl2 Gas and CCl4 Vapor

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Hot bands were resolved in the vibrational Raman spectrum of chlorine at atmospheric pressure. The anharmonicity constant is in good agreement with the value obtained from absorption spectra. In carbon tetrachloride vapor the hot bands contributing the the ν1 band contour were investigated from 25° to 130°C.

Keywords: Anharmonicity; Hot bands; Raman spectra of gases

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/000370271779949168

Affiliations: Sektion Physik der Universität München, Lehrstuhl J. Brandmüller, Munich, Germany

Publication date: May 1, 1971

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