Metal Isotope Effect on Raman Spectrum of [Zn(NH3)4]I2 Crystals

Authors: Nakamoto, Kazuo1; Takemoto, James1; Chow, T. L.2

Source: Applied Spectroscopy, Volume 25, Issue 3, Pages 293-383 (May/June 1971) , pp. 352-355(4)

Publisher: Society for Applied Spectroscopy

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Abstract:

The Raman spectra of [64Zn(NH3)4]I2 and its 68Zn analog have been measured in the crystalline state. The Zn–N stretching vibrations have been assigned based on the observed metal isotope shifts. These shifts have been compared with theoretical values obtained from a complete normal coordinate analysis on the [Zn(NH3)4]2+ ion.

Keywords: Metal isotope effect; Raman spectrum; Tetrammine zinc(II) iodide

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/000370271779949195

Affiliations: 1: The Todd Wehr Chemistry Building, Marquette University, Milwaukee, Wisconsin 53233 2: The Todd Wehr Chemistry Building, Marquette University, Milwaukee, Wisconsin 53233; present address: Department of Chemistry, Illinois Institute of Technology, Technology Center, Chicago, Ill. 60616

Publication date: May 1, 1971

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