Vibrational Spectra of bis-(Maleonitrile Dithiolato)Ni(II) Anion

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Abstract:

The in-plane normal modes of bis-(maleonitriledithiolato)Ni(II) anion have been assigned on the basis of the normal coordinate analysis. The potential energy distribution among various internal coordinates indicates a large amount of vibrational mixing. The value of K(C-S) suggests a considerable amount of double bond character.

Keywords: Coordination compounds; Infrared spectra; Vibrational analysis

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/000370271779948754

Affiliations: Department of Chemistry, Indian Institute of Technology, Kanpur, India

Publication date: March 1, 1971

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