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Far Infrared and Raman Spectra of (CH3)3SiCo(CO)4

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Abstract:

The ir spectra of (CH3)3SiCo(CO)4 in the gaseous (4000–250 cm−1) and solid (4000–33 cm−1) phases have been recorded. The Raman spectrum has also been recorded for the solid state. To aid in the assignment, the ir and Raman spectra were recorded of solid (CH3)3SiH. The vibrational assignment for most of the 60 normal modes has been given on the basis of the fundamental vibrations of the –Si(CH3)3 and –Co(CO)4 moities. The static field was sufficiently strong to split the degenerate modes but the correlation field was so weak that no definite splitting of the symmetric modes was detected.

Keywords: Far infrared spectra; Infrared spectra; Raman spectra

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/000370271779948565

Affiliations: 1: Department of Chemistry, University of South Carolina, Columbia, South Carolina 29208 2: Department of Chemistry, University of South Carolina, Columbia, South Carolina 29208; present address: Department of Chemistry, Aurora College Aurora, Ill. 60507

Publication date: March 1, 1971

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