The absorption spectra of some organic azides have been studied in the visible and uv region using different solvents. Interpretation of the obtained results is attempted. The different transitions obtained are assigned to either intramolecular charge–transfer transitions or to
locally excited ones. The energies of the charge–transfer states are computed. No evidence was found for an n → π* transitión.
Chemistry Department, Faculty of Science, Cairo University, Egypt, United Arab Republic
Publication date: January 1, 1971
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