Metal Isotope and High Pressure Effects on the Infrared Active Skeletal Vibrations in Metal Sandwich Compounds

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Abstract:

Metal sandwich compounds such as ferrocene (FeCp2) and ruthenocene (RuCp2) exhibit the six skeletal modes shown in Fig. 1. Among them, the ring tilt (v 5), the metal–ring stretch (v 3), and the ring–metal–ring bending (v 6) are infrared active under D 5h (or D 5d) symmetry.

Keywords: Assignments; High pressure effects; Metallocenes; Metals isotope effects

Document Type: Short Communication

DOI: http://dx.doi.org/10.1366/000370270774372452

Affiliations: 1: Argonne National Laboratory, Argonne, Illinois 60439; Consultant to Argonne National Laboratory from Chemistry; Consultant to Argonne National Laboratory from Chemistry Department, Marquette University, Milwaukee, Wisc. 53233 2: Argonne National Laboratory, Argonne, Illinois 60439; Postdoctoral fellow, Chemistry Department, Marquette University, Milwaukee, Wisc. 53233 3: Argonne National Laboratory, Argonne, Illinois 60439

Publication date: November 1, 1970

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