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The Polarized Infrared Spectra of Hydroxyl Ion in Fluorapatite

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Abstract:

The major components of the ir spectra of fluorapatite [Ca10(PO4)6F2] and hydroxyapatite [Ca10(PO4)6(OH)2] have been observed and analyzed by many investigators. In the present investigation, the polarized ir spectra of thin crystal sections of geological fluorapatite have been obtained in the region from 4000 to 1800 cm−1. On the basis of these spectra, the orientation of impurity hydroxyl ions trapped within the fluorapatite lattice has been suggested.

Keywords: Apatite; Infrared spectroscopy

Document Type: Short Communication

DOI: http://dx.doi.org/10.1366/000370270774371741

Affiliations: 1: Department of Ceramic Science, College of Ceramics, Alfred University, Alfred, New York 14802; present address: Ferro Corporation, Technical Center, 4150 E. 56th Street, Cleveland, Ohio 44105 2: Department of Ceramic Science, College of Ceramics, Alfred University, Alfred, New York 14802

Publication date: March 1, 1970

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