n-π* Electronic Emission and Absorption Spectra of o-Fluorobenzaldehyde in Vapor Phase

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Abstract:

The electronic emission and absorption spectra of o-fluorobenzaldehyde have been studied. The emission spectrum recorded on a Fuess glass and a medium quartz spectrograph lies in the region 26 668–17 862 cm−1 and the absorption spectrum recorded on a Zeiss Q–24 medium quartz spectrograph lies in the region 30 995–24 610 cm−1. The O-O band has been observed at 26 337 cm−1. The C=O stretching frequency 1733 cm−1 in the ground state and 1355 cm−1 in the excited state is most intense and forms progressions of bands both in the emission and absorption spectra. The observed bands have been interpreted as combinations of the C=O stretching frequency and its multiples with other fundamentals. The transition involved is A'–A" (n-π*).

Keywords: Absorption spectra; Electronic emission spectra; Visible and ultraviolet spectroscopy

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/000370270774372119

Affiliations: Department of Spectroscopy, Banaras Hindu University, Varanasi-5, India

Publication date: January 1, 1970

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