Far-Infrared and Raman Spectra of Ammonium Fluoride and Ammonium Fluoride–d 4

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Abstract:

The far-infrared spectra of thin films of NH4F and ND4F and the Raman spectra of polycrystalline samples of both compounds have been recorded at -170°C. Two low-frequency lattice vibrations were observed in each spectrum and these have been assigned as optical translations on the basis of their isotopic shift factors. Librational modes were not observed in any of the spectra.

Keywords: Ammonium fluoride; Far-infrared spectra; Raman spectra

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/000370270774372227

Affiliations: 1: Department of Chemistry, University of South Carolina, Columbia, South Carolina 29208 2: Department of Chemistry, University of South Carolina, Columbia, South Carolina 29208; present address: E. I. duPont de Nemours and Company, Kinston, North Carolina

Publication date: January 1, 1970

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