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Infrared Spectroscopy at Sub-Ambient Temperatures: III. Molecules and Molecular Fragments within Matrices

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The practical and theoretical aspects of infrared spectroscopy of molecules and molecular fragments within matrices at low temperatures are discussed in detail. The following subjects are included in this discussion: the materials used for matrices, the history of the matrix-isolation method of preparation of matrices, unique features of the MIM, problems of the MIM, applications of the MIM, and mathematical models. This paper also discusses pressure and liquid-induced infrared spectra at low temperatures.

Keywords: Infrared spectroscopy; Liquid induced spectra; Low temperatures; Mathematical models; Matrix isolation; Pressure induced spectra

Document Type: Review Article

DOI: http://dx.doi.org/10.1366/000370269774380464

Affiliations: Midwest Research Institute, Kansas City, Missouri 64110

Publication date: September 1, 1969

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