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The Chemistry of Trifluoroamine Oxide. IV. The Infrared Spectra of F3 14NO AND F3 15NO

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The infrared spectra of trifluoroamine oxide and its 15N analogue have been measured from 4000 to 260 cm−1. Fundamental frequency assignments (based upon C3v symmetry) made from the 14N spectrum are: v 1(a 1) = 1689, v 2(a 1)= 740, v 3 (a 1) = 528, v 4(e) = 880, and v 6(e) = 398 cm−1. Normal coordinate calculations support the assignment of the remaining fundamental v 5(e) to a band system appearing as a shoulder, about 558 cm−1, on the intense v 3(a 1) fundamental.

Keywords: Frequency assignments; Infrared spectra; Trifluoroamine oxide

Document Type: Research Article


Affiliations: Morristown Research Laboratory, Industrial Chemicals Division, Allied Chemical Corporation, Morristown, New Jersey 17960

Publication date: July 1, 1969

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