Vibrational Spectra of Bis-(monothioacetylacetonato) Ni(II)

$29.00 plus tax (Refund Policy)

Buy Article:

Abstract:

The infrared spectra of substituted acetylacetonates have been discussed in the light of normal coordinate analysis of bis-(monothioacetylacetonato) Ni(II) assuming methyl groups as point masses. The Urey-Bradley potential constants evaluated are found to be quite close to those of analogous systems studied earlier. The calculations show that each of the fundamental bands results from vibrational modes involving appreciable contributions from a number of bonds. The single major contribution from the stretching of C = S has been found in the 723 cm−1 band. This is in agreement with the other conjugated systems, like thioamides, studied earlier.

Keywords: Bis-(monothioacetylacetonate) Ni(II) complex; Infrared spectra: Normal coordinate treatment

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/000370269774380978

Affiliations: Department of Chemistry, Indian Institute of Technology, Kanpur, India

Publication date: May 1, 1969

More about this publication?
Related content

Tools

Favourites

Share Content

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
Cookie Policy
X
Cookie Policy
ingentaconnect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more