Transition Metal(II) Complexes of the Azines

Authors: Ferraro, J.R.¹; Zipper, J.²; Wozniak, W.³

Source: Applied Spectroscopy, Volume 23, Issue 2, Pages 105-174 (March/April 1969) , pp. 160-164(5)

Publisher: Society for Applied Spectroscopy

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Abstract:

The complexes of the Mn (II), Fe (II), Co(II), Ni(II), and Cu(II) halides with pyrazine (1,4-diazine), pyrimidine (1,3-diazine), and pyridazine (1,2-diazine) were prepared and studied by various physical methods. Reflectance spectra, infrared spectra from 4000-80 cm⁻¹, and magnetic moments were determined. The data are suggestive of an octahedral environment involving halide and azine bridging in the 1: 1 complexes, and an octahedral environment involving halide bridging and terminal azines in the 1: 2 complexes.

Document Type: Research article

DOI: http://dx.doi.org/10.1366/000370269774381120

Affiliations: 1: Argonne National Laboratory, Argonne, Illinois 60439 2: Argonne National Laboratory, Argonne, Illinois 60439; present address: Purdue University, Graduate School of Chemistry, Lafayette, Indiana 3: Argonne National Laboratory, Argonne, Illinois 60439; present address: Florida State University, Graduate School of Chemistry, Tallahassee, Florida

Publication date: 1969-03-01

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