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Raman Apparatus Using Laser Excitation and Polarization Measurements. Rotational Spectrum of Fluorine

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Abstract:

Various schemes are compared for measuring depolarization factors in Raman spectra with laser excitation. Optical systems are discussed for producing a laser beam free of unwanted emission lines and for focusing scattered light on the slit and on the detector. The rotational spectrum of gaseous F2 has been used to determine a rotational constant of B 0=0.8841±0.0006 cm−1, corresponding to r 0=1.4168±0.0005 Å.

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/000370269774381265

Affiliations: 1: Department of Inorganic and Analytical Chemistry, The Hebrew University of Jerusalem, Jerusalem, Israel; present address: Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439 2: Department of Inorganic and Analytical Chemistry, The Hebrew University of Jerusalem, Jerusalem, Israel

Publication date: January 1, 1969

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