Use of Alkyl-Bending Vibration Frequencies as an Aid in the Characterization of Alkyladamantane Structures

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Abstract:

We have previously shown that bridgehead-substituted methyl and ethyl adamantanes can be characterized and identified using a combination of infrared and nuclear-magnetic-resonance (NMR) spectroscopy and mass spectrometry. Although NMR is the most useful diagnostic tool in alkyladamantane structural determinations, the infrared spectra exhibit certain diagnostically useful medium-intensity absorption bands in the 1338–1385-cm−1 region.

Document Type: Short Communication

DOI: http://dx.doi.org/10.1366/000370268774383697

Affiliations: Sun Oil Co., Marcus Hook, Pennsylvania 19061

Publication date: January 1, 1968

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