Absorption Spectrum of Fluorine Azide

Authors: Gipstein, Edward¹; Haller, John F.²

Source: Applied Spectroscopy, Volume 20, Issue 6, Pages 359-423 (November/December 1966) , pp. 417-418(2)

Publisher: Society for Applied Spectroscopy

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Abstract:

Fluorine azide was first prepared by Haller as a reaction product of hydrogen azide and fluorine. It is described as a greenish-yellow gas at room temperature, liquefying at −82°C when diluted with nitrogen and freezing to a yellow solid at −143°C. Evaporation of this solid generally results in violent explosion. However, gaseous fluorine azide decomposes slowly at room temperature and very rapidly at 100°C without explosion. Difluorodiazene (N₂F₂) and nitrogen are formed.

Document Type: Short communication

DOI: http://dx.doi.org/10.1366/000370266774386470

Affiliations: 1: Olin Mathieson Chemical Corporation, New Haven, Connecticut; present address: IBM Research Laboratory, San Jose, Calif. 95114 2: Olin Mathieson Chemical Corporation, New Haven, Connecticut; present address: Deland, Fla.

Publication date: 1966-11-01

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