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Spectroscopic Studies of Substituted Benzalanilines

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Ultraviolet and visible spectra are reported for 28 N-benzylidineanilines with their molar absorptivities given in absolute ethanol, and in isooctane when feasible. Infrared studies in the 2-15 micron region are reported for these compounds and also for three newly synthesized N-d-benzylidineanilines. With the aid of these deuterated benzalanilines, infrared assignments are given for the frequencies characteristic of the center – CH=N-azomethine group. The ultraviolet and infrared spectra are compared in relation to the reported basicity of their azomethine groups.

Document Type: Research Article


Affiliations: 1: Pioneering Research Division, Quartermaster Research and Engineering Center, Natick, Massachusetts; present address: Hughes Research Laboratories, Malibu, Califorma (Contribution from the Pioneering Research Division of the Quarter-master Research and Engineering Center, Natick, Massachusetts) 2: Pioneering Research Division, Quartermaster Research and Engineering Center, Natick, Massachusetts

Publication date: May 1, 1965

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