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The Far Infrared Spectra of Monosubstituted Pyridines

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Abstract:

Infrared spectra in the cesium bromide region are presented for 43 monosubstituted pyridines. Two- and 3-substituted pyridines are characterized in this region by two relatively intense bands near 600 and 400 cm−1. No strong characteristic bands are found for 4-substituted pyridines. The vapor-phase contours of the far infrared bands of 2-fluoro- and 2-chloropyridine indicate that the 600 and 400 cm−1 bands arise, respectively, from an in-plane and an out-of-plane vibration. The pyridine spectra are compared with the spectra of some substituted benzenes.

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/000370263789621097

Affiliations: 1: Materials Central, Aeronautical Systems Division, Wright-Patterson Air Force Base, Ohio; present address: Chemical Operations, Thiokol Chemical Corp, Trenton, N. J. 2: Materials Central, Aeronautical Systems Division, Wright-Patterson Air Force Base, Ohio 3: Southern Research Institute, Birmingham, Alabama

Publication date: July 1, 1963

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