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Slopes of Working Curves in Emission Spectrometric Analysis of Certain Silicates

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In the emission spectrometric analysis of silicates, Strock recently reported large deviations from unity of the working curve slopes He suggested that these abnormal slopes resulted from collisions of the second kind occurring in the direct-curent arc discharge. These experiments were repeated, and data were treated statistically. Deviations from a slope of unity in nearly every case were satisfactorily explained by the experimental errors inherent in the method or by self-absorption.

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/000370259774614807

Affiliations: Department of Mines and Technical Surveys, Ottawa, Canada; present address: Applied Research Laboratory, United States Steel Corporation, Monroeville, Pennsylvania

Publication date: October 1, 1959

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