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Determination of Cerium in Ferrous Alloys

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Abstract:

The method is applicable to the determination of cerium in cast iron, carbon and stainless steel. The cerium is co-precipitated with barium as fluorides in an hydrochloric-perchloric acid solution. The ignited precipitate is analyzed spectrographically using the D.C. arc. The lowest detectable amount is of the order of .003% cerium for stainless and somewhat lower for iron and steel.

Synthetic standards for comparison are made by the addition of a standardized cerium solution to a cerium-free alloy similar to the unknown and then carried through the procedure simultaneously.

Document Type: Research Article

DOI: http://dx.doi.org/10.1366/000370253774634711

Affiliations: Chemical Laboratory, South Works, U. S. Steel Corp.

Publication date: November 1, 1953

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