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Iron, Copper, and Manganese Complexation by Forest Leaf Litter

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Natural and acid-treated leaf litter samples from western white pine (Pinus monticola), willow (Salix Sp.), and chinquapin (Castanopsis sempervirens) and their laboratory-prepared complexes with Fe3+, Cu2+, and Mn2+ were characterized chemically by total metal analysis, infrared (IR) spectroscopy, and electron spin resonance (ESR) spectroscopy. Both the natural and the acid-treated litter samples took up large amounts of Fe, Cu, and Mn from 0.1M solutions, complexing the metals in forms of differing stability against extensive water-washing and proton- or metal-exchange treatments. The IR spectra indicated that carboxyl groups were the most important metal-binding sites in the litter samples. The ESR data showed that the complexes of M2+ involved principally electrostatic forces between the hydrated metal ion and oxygen-containing litter ligands. These complexes were water stable at neutral pH, but easily disrupted by proton or metal exchange. The litter samples bound Fe3+ and, to a lesser extent, Cu2+ in highly water-stable complexes involving direct metal ion contact with oxygen-containing litter ligands. Some of these complexes were resistant to highly acidic conditions or to metal exchange, although reversibility was evident when they were reacted with solutions of differing pH or metal composition. Good correlation existed between trends in total metal content and the ESR data for the metal-litter products obtained after various treatments, suggesting that the metal-litter complexes detected spectroscopically were representative of the dominant speciation of the metals in the litter. For. Sci. 35(4):1040-1057.

Keywords: Copper-organic complexes; iron-organic complexes; manganese-organic complexes; metal cycling

Document Type: Journal Article

Affiliations: Specialist, Department of Soil and Environmental Sciences, University of California, Riverside, CA 92521

Publication date: 1989-12-01

More about this publication?
  • Forest Science is a peer-reviewed journal publishing fundamental and applied research that explores all aspects of natural and social sciences as they apply to the function and management of the forested ecosystems of the world. Topics include silviculture, forest management, biometrics, economics, entomology & pathology, fire & fuels management, forest ecology, genetics & tree improvement, geospatial technologies, harvesting & utilization, landscape ecology, operations research, forest policy, physiology, recreation, social sciences, soils & hydrology, and wildlife management.
    Forest Science is published bimonthly in February, April, June, August, October, and December.

    2015 Impact Factor: 1.702
    Ranking: 16 of 66 in forestry

    Average time from submission to first decision: 62.5 days*
    June 1, 2016 to Feb. 28, 2017

    Also published by SAF:
    Journal of Forestry
    Other SAF Publications
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