Solution and solid-state characterization of a dicopper receptor for large substrates

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Ligand 2 contains two metal-binding domains separated by a rigid spacer and assembles into a dicopper receptor with a large central cavity with no evidence of catenation.Key words: copper complex, coordination, X-ray crystallography, molecular recognition.

Le ligand 2 contient deux groupement pour coordonner des métaux séparer par un espaceur rigide et s'auto-assemble avec le cuivre(II) pour former un récepteur avec un grand cavité centrale avec aucune evidence pour la formation de caténane.Mots clés : complex de cuivre, coordination, crystallographie rayons-X, reconnaissance moléculaire.
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