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Solution and solid-state characterization of a dicopper receptor for large substrates

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Ligand 2 contains two metal-binding domains separated by a rigid spacer and assembles into a dicopper receptor with a large central cavity with no evidence of catenation.Key words: copper complex, coordination, X-ray crystallography, molecular recognition.

Le ligand 2 contient deux groupement pour coordonner des métaux séparer par un espaceur rigide et s'auto-assemble avec le cuivre(II) pour former un récepteur avec un grand cavité centrale avec aucune evidence pour la formation de caténane.Mots clés : complex de cuivre, coordination, crystallographie rayons-X, reconnaissance moléculaire.

Keywords: X-ray crystallography; complex de cuivre; coordination; copper complex; crystallographie rayons-X; molecular recognition; reconnaissance moléculaire

Document Type: Research Article

Publication date: 2002-05-01

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  • Published since 1929, this monthly journal reports current research findings in all branches of chemistry. It includes the traditional areas of analytical, inorganic, organic, and physical-theoretical chemistry and newer interdisciplinary areas such as materials science, spectroscopy, chemical physics, and biological, medicinal and environmental chemistry. Full papers, preliminary communications and review articles are all welcomed.
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