Skip to main content

Complexly zoned niobian titanite from hedenbergite skarn at Písek, Czech Republic, constrained by substitutions Al(Nb,Ta)Ti−2, Al(F,OH)(TiO)−1 and SnTi−1

Buy Article:

$13.61 plus tax (Refund Policy)

Abstract:

Euhedral crystals of complexly zoned niobian titanite (up to 0.3 mm) are enclosed in hedenbergite (Hd53–81Di15–43Jh3–5) and quartz from a hedenbergite vein skarn at Kamenné doly near Písek, Czech Republic. They are associated with minor clinozoisite-epidote (Ps3–22), calcite, plagioclase (An95), scapolite (Me80–82), scheelite, pyrrhotite, fluorapatite, arsenopyrite, native bismuth and Bi, Te-minerals. The following textural and compositional subtypes were recognized: (I) Nb-rich titanite, (II) Nb-moderate titanite in the central zone, (III) Nb-poor, Sn-enriched titanite and (IV) Nb-poor, Al,F-rich titanite in the outer zone. The substitution Al(Nb,Ta)Ti−2 is dominant in subtypes I and II, the titanite subtype I being characterized by elevated contents of Al ≤ 0.257 atoms per formula unit (a.p.f.u.), Nb (≤0.161 a.p.f.u.) and Ta (≤0.037 a.p.f.u.). Amounts of Al, Nb and Ta in subtype II are smaller and more variable. The minor substitution SnTi−1 occurs chiefly in titanite subtype III with a content of Sn ≤0.039 a.p.f.u.. The substitution Al(F,OH)(TiO)−1 is typical for titanite subtype IV exhibiting elevated contents of Al (≤0.221 a.p.f.u.), F (≤0.196 a.p.f.u.) and Fe (≤0.039 a.p.f.u.).

The negative relationship of substitutions Al(F,OH)(TiO)−1 vs. SnTi−1 and Al(Nb,Ta)Ti−2 is constrained chiefly by crystal structure rather than by the composition of parent medium alone. Textural relations suggest that the Nb-moderate titanite in the core zone and entire outer zone are products of fluids-induced dissolution-reprecipitation processes. The studied niobian titanite represents a new F-enriched type from a medium-grade, calc-silicate rock.

Keywords: ALUMINIUM; CZECH REPUBLIC; ELECTRON MICROPROBE; FLUORINE; MOLDANUBIAN; NIOBIUM; SKARN; SUBSTITUTIONS; TIN; TITANITE; ZONE

Document Type: Research Article

DOI: http://dx.doi.org/10.1180/minmag.2008.072.6.1293

Publication date: December 1, 2008

More about this publication?
minsoc/mag/2008/00000072/00000006/art00010
dcterms_title,dcterms_description,pub_keyword
6
5
20
40
5

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
UA-1313315-23
Cookie Policy
X
Cookie Policy
Ingenta Connect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more