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Removal of Mg from spring water using natural clinoptilolite

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Abstract:

Natural zeolitic tuff from Brus (Serbia) consisting mostly of clinoptilolite (about 90%) has been investigated for the reduction of the Mg concentration in spring water. The sorption capacity of the zeolite is relatively low (about 2.5 mg Mg g−1 for the initial concentration of 100 mg Mg dm−3). The zeolitic tuff removes Mg from water solutions by ion exchange, which has been demonstrated by energy dispersive X-ray analysis (EDS). The extent of ion exchange was influenced by the pH and the initial Mg concentration. Kinetic studies revealed that Lagergen's pseudo-second order model was followed. Intra-particle diffusion of Mg2+ influenced the ion exchange, but it is not the rate-limiting step. Rather than having to dispose of the Mg-loaded (waste) zeolite, a possible application was tested. Addition to a wastewater with a low concentration of Mg showed that it could successfully make up for the lack of Mg micronutrient and, accordingly, enabled the growth of phosphate-accumulating bacteria A. Junii, increasing the amount of phosphate removed from the wastewater.

Keywords: BACTERIA; BRUS; CLINOPTILOLITE; IGROS VIDOJEVIC DEPOSIT; MG REMOVAL; NATURAL ZEOLITE; SERBIA; WATER SOFTENING

Document Type: Research Article

DOI: http://dx.doi.org/10.1180/claymin.2012.047.1.81

Publication date: March 1, 2012

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