Transformation of magnetite to goethite under alkaline pH conditions

$14.04 plus tax (Refund Policy)

Buy Article:

Abstract:

Magnetite is a redox active Fe oxide common in most soil and sedimentary environments. In this study, we investigated magnetite transformations under extreme alkaline conditions (0.1−2 mol l−1 NaOH) similar to those found under high-level radioactive waste storage tanks at the Hanford site in the State of Washington, USA. X-ray diffraction (XRD) and transmission electron microscopy (TEM) results showed that magnetite was transformed into maghemite and goethite, and the XRD peak intensities for goethite increased with NaOH concentration. Goethite was presumably formed through reconstructive dissolution/crystallization reactions that can be written as: Fe3O4 + OH + H2O = -Fe2O3 + Fe(OH)3; 2Fe(OH)3 + ┬ŻO2 + 2H+ = 2α-FeOOH + 3H2O. Some of the newly formed maghemite may also redissolve to form goethite at greater NaOH concentrations.
More about this publication?
Related content

Tools

Favourites

Share Content

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
UA-1313315-23
Cookie Policy
X
Cookie Policy
ingentaconnect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more