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Iron (III)-doped montmorillonite catalysis of alkenes bearing sulphoxide groups in Diels-Alder reactions

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Abstract:

Fe3+-doped K10 montmorillonite combined with 2,6-di-tert-butyl-4-methyl-phenol is a potent catalytic system for trans-2-methylene-1,3-dithiolane 1,3-dioxide as a dienophile. Cycloaddition occurs with cyclopentadiene and furan as a diene at room temperature in short time and with good yields (64% overall).

Keywords: KETENE EQUIVALENTS; MONTMORILLONITE; [4+2]-CYCLOADDITIONS

Document Type: Research Article

DOI: https://doi.org/10.1180/0009855043930139

Publication date: 2004-09-01

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