Intercalation of tris(2,2'-bipyridine)ruthenium(II) into magadiite

$14.96 plus tax (Refund Policy)

Buy Article:

Abstract:

Intercalation of the tris(2,2'-bipyridine)ruthenium(II) complex cation into a layered silicate (magadiite; the ideal formula for which is Na2Si14O29nH2O) was investigated. Since the complex cation did not intercalate by a direct ion exchange reaction with the interlayer Na ions in an aqueous medium, dodecyltrimethylammonium exchanged magadiite was used as a precursor. Depending on the loading of the complex cations and the solvents employed for the reactions, two types of tris(2,2'-bipyridine)ruthenium(II)-magadiite intercalation compounds formed. One has a basal spacing of ~2.9 nm due to a large amount of the dodecyltrimethylammonium ions which remained in the interlayer space of magadiite and coexisted with the intercalated tris(2,2'bipyridine)ruthenium(II) complex cations. The other has a basal spacing of ~2.0 nm because the intercalated tris(2,2'-bipyridine)ruthenium(II) complex ions form a monolayer in the interlayer space of magadiite.

Document Type: Research Article

DOI: http://dx.doi.org/10.1180/000985598545796

Affiliations: 1: PRESTO, Japan Science and Technology Corporation, and Institute of Earth Science, Waseda University, Nishiwaseda 1-6-1, Tokyo 169-50, Japan 2: Institute of Earth Science, Waseda University, Nishiwaseda 1-6-1, Tokyo 169-50, Japan

Publication date: December 1, 1998

More about this publication?
Related content

Tools

Favourites

Share Content

Access Key

Free Content
Free content
New Content
New content
Open Access Content
Open access content
Subscribed Content
Subscribed content
Free Trial Content
Free trial content
UA-1313315-23
Cookie Policy
X
Cookie Policy
ingentaconnect website makes use of cookies so as to keep track of data that you have filled in. I am Happy with this Find out more