Review and recommended thermodynamic properties of FeCO₃

Authors: P. L. Fosbøl, K. Thomsen, E. H. Stenby

Source: Corrosion Engineering, Science and Technology

Publisher: Maney Publishing

Abstract:

An extensive review of entropy, enthalpy of formation and Gibbs energy of formation, heat capacity, aqueous solubility and solubility constant of FeCO₃ is given. A consistent set of thermodynamic properties for FeCO₃ and relevant aqueous species is selected and recommended for use. Speciation schemes for aqueous FeCO₃ are reviewed and evaluated. Issues related to supersaturation of FeCO₃ are discussed. Works on the thermal decomposition of FeCO₃ are presented and an overview of measured solubility and synthesis of FeCO₃ is given.

Document Type:

DOI: 10.1179/174327808X286437

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