Authors: Shagun V.A.; Shagun L.G.; Voronkov M.G.

Source: Russian Journal of General Chemistry, Volume 74, Number 4, April 2004 , pp. 594-599(6)

Publisher: MAIK Nauka/Interperiodica

Abstract:

The mechanism of formation of -halo thioketones in reactions of haloacetones with H₂S in the presence of HCl was studied by quantum-chemical methods. The cause of failure in attempted preparation of iodo thioketone by this procedure was elucidated. The stereoelectronic structure and capability for 1,3-proto- tropic rearrangements of -halothioacetones were studied.

Document Type: Research article

DOI: http://dx.doi.org/10.1023/B:RUGC.0000031863.18689.0d

Affiliations: 1: Favorskii Irkutsk Institute of Chemistry, Siberian Division, Russian Academy of Sciences, Irkutsk, Russia

Publication date: 2004-04-01

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