Mechanism of Formation and Molecular Structure of -Halothioacetones
Authors: Shagun V.A.; Shagun L.G.; Voronkov M.G.
Source: Russian Journal of General Chemistry, Volume 74, Number 4, April 2004 , pp. 594-599(6)
Publisher: MAIK Nauka/Interperiodica
Abstract:The mechanism of formation of -halo thioketones in reactions of haloacetones with H2S in the presence of HCl was studied by quantum-chemical methods. The cause of failure in attempted preparation of iodo thioketone by this procedure was elucidated. The stereoelectronic structure and capability for 1,3-proto- tropic rearrangements of -halothioacetones were studied.
Document Type: Research article
Publication date: 2004-04-01