Thermal Decomposition of Secondary N-nitramines Having 1,2,4-Triasole and Tetrazole Substituents

Authors: Stepanov R.S.; Astakhov A.M.; Kruglyakova L.A.; Nefedov A.A.

Source: Russian Journal of General Chemistry, Volume 72, Number 8, August 2002 , pp. 1291-1293(3)

Publisher: MAIK Nauka/Interperiodica

Abstract:

Thermal decomposition of secondary N-nitramines having azole substituents in the position is faster by almost two orders of magnitude than the decomposition of -substituted analogs. The rate-determining stage is homolytic dissociation of the NÄNO₂ bond. An alternative route of thermal decomposition of -tetrazolyl-substituted N-nitramines involves initial clavage of the tetrazole ring.

Language: English

Document Type: Research article

Affiliations: 1: Siberian State Technological University, Krasnoyarsk, Russia

Publication date: 2002-08-01

• In this: publication
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• In this Subject: Chemistry (General)
• By this author: Stepanov R.S. ;  Astakhov A.M. ;  Kruglyakova L.A. ;  Nefedov A.A.

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