Kinetics and Mechanism of Liquid-Phase Thermal Decomposition of -Cyanoethyl-N-nitramines
Authors: Stepanov, R.S.; Astakhov, A.M.; Kruglyakova, L.A.; Pekhotin, K.V.
Source: Russian Journal of General Chemistry, Volume 72, Number 8, August 2002 , pp. 1256-1258(3)
Publisher: MAIK Nauka/Interperiodica
Abstract:Termal decomposition of -cyanoethyl-N-nitramine in melt is preceded by protonation of the amino nitrogen atom and is accompanied by evolution of nitrogen(I) oxide with formation of acrylonitrile. Thermal decomposition of bis(-cyanoethyl)-N-nitramine under similar conditions follows a radical mechanism with initial dissociation of the NÄN bond. The same mechanism is operative in thermal decomposition of both N-nitramines in a dilute dibutyl phthalate solution.
Document Type: Research Article
Affiliations: Siberian State Technological University, Kranoyarsk, Russia
Publication date: August 1, 2002