Synthesis and structure of phenylbismuth bis(chloroacetate)
Authors: Egorova, I.; Sharutin, V.; Ivanenko, T.; Nikolaeva, N.; Molokov, A.
Source: Russian Journal of Coordination Chemistry, Volume 32, Number 5, May 2006 , pp. 321-324(4)
Publisher: MAIK Nauka/Interperiodica
Abstract:Crystals of phenylbismuth bis(chloroacetate) were synthesized by the reaction of triphenylbismuth with chloroacetic acid. Tridentate chelate-bridging chloroacetate ligands are bonded to neighboring molecules through the O atoms to form polymer chains. The Bi-O distances are equal to 2.36(1), 2.55(1), 2.78(1) and 2.30(1), 2.67(1), 2.85(2) Å. the length of the Bi-C bond is 2.26(2) Å.
Document Type: Research Article
Publication date: May 1, 2006